Watching two-dimensional materials grow

Atomically thin crystals will play an ever greater role in future – but how can their crystallization process be controlled? A new method is now opening up new possibilities.

They are among the thinnest structures on earth: “two dimensional materials” are crystals which consist of only one or a few layers of atoms. They often display unusual properties, promising many new applications in opto-electronics and energy technology. One of these materials is 2D-molybdenum sulphide, an atomically thin layer of molybdenum and sulphur atoms.

The production of such ultra-thin crystals is difficult. The crystallisation process depends on many different factors. In the past, different techniques have yielded quite diverse results, but the reasons for this could not be accurately explained. Thanks to a new method developed by research teams at TU Wien, the University of Vienna and Joanneum Research in Styria, for the first time ever it is now possible to observe the crystallisation process directly under the electron microscope. The method has now been presented in the scientific journal ‘ACS nano’.

From gas to crystal

“Molybdenum sulphide can be used in transparent and flexible solar cells or for sustainably generating hydrogen for energy storage”, says the lead author of the study, Bernhard C. Bayer from the Institute of Materials Chemistry at TU Wien. “In order to do this, however, high-quality crystals must be grown under controlled conditions.”

Usually this is done by starting out with atoms in gaseous form and then condensing them on a surface in a random and unstructured way. In a second step, the atoms are arranged in regular crystal form – through heating, for example. “The diverse chemical reactions during the crystallisation process are, however, still unclear, which makes it very difficult to develop better production methods for 2D materials of this kind”, Bayer states.

Thanks to a new method, however, it should now be possible to accurately study the details of the crystallisation process. “This means it is no longer necessary to experiment through trial and error, but thanks to a deeper understanding of the processes, we can say for certain how to obtain the desired product”, Bayer adds.

Graphene as a substrate

First, molybdenum and sulphur are placed randomly on a membrane made of graphene. Graphene is probably the best known of the 2D materials – a crystal with a thickness of only one atom layer consisting of carbon atoms arranged in a honeycomb lattice. The randomly arranged molybdenum and sulphur atoms are then manipulated in the electron microscope with a fine electron beam. The same electron beam can be used simultaneously to image the process and to initiate the crystallization process.

That way it has now become possible for the first time to directly observe how the atoms move and rearrange during the growth of the material with a thickness of only two atomic layers. “In doing so, we can see that the most thermodynamically stable configuration doesn't necessarily always have to be the final state”, Bayer says. Different crystal arrangements compete with one another, transform into each other and replace one another. “Therefore, it is now clear why earlier investigations had such varying results. We are dealing with a complex, dynamic process.” The new findings will help to adapt the structure of the 2D materials more precisely to application requirements in future by interfering with the rearrangement processes in a targeted manner.

Original publication:

Bayer et al.; "Atomic-Scale in Situ Observations of Crystallization and Restructuring Processes in Two-Dimensional MoS2 Films"; ACS Nano; 2018