What is Covalent bond
A covalent bond, also called a molecular bond, is a chemical bond that
involves the sharing of electron pairs between atoms. These electron pairs are
known as shared
pairs or bonding pairs, and the stable balance of attractive
and repulsive forces between atoms, when they share electrons, is known as
covalent bonding. For many molecules, the sharing of electrons allows each atom
to attain the equivalent of a full outer shell, corresponding to a stable
electronic configuration.
Covalent bonding includes many kinds of interactions, including
σ-bonding, π-bonding, metal-to-metal bonding, agostic interactions, bent bonds,
and three-center two-electron bonds.
The term covalent bond dates from
1939.
The prefix co- means jointly,
associated in action, partnered to a lesser degree, etc.; thus a
"co-valent bond", in essence, means that the atoms share
"valence", such as is discussed in valence bond theory.
In the molecule H
2, the hydrogen atoms share the two electrons via covalent bonding.
Covalency is greatest between
atoms of similar electronegativities. Thus, covalent bonding does not
necessarily require that the two atoms be of the same elements, only that they
be of comparable electronegativity. Covalent bonding that entails sharing of
electrons over more than two atoms is said to be delocalized.
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